Slow dynamics and aging in colloidal gels studied by x-ray photon correlation spectroscopy

Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Jul;76(1 Pt 1):010401. doi: 10.1103/PhysRevE.76.010401. Epub 2007 Jul 2.

Abstract

Slow, nonequilibrium dynamics during delayed sedimentation in a colloidal depletion gel was studied by x-ray photon correlation spectroscopy. The intermediate scattering functions change during the process from stretched to compressed exponential decays, indicating a jamming transition toward full aging. A complex aging behavior follows this process; it is proposed that large-scale network deformations trigger an unjamming, leading to the final collapse of the gel.