Abstract
A variety of 5-alkylsalicylates, 5-alkyl-2-hydroxy-acetophenones, and 5-alkyl-2-hydroxy-benzophenones was regioselectively prepared by TiCl4 mediated formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 2-alkyl-1,1,3,3-tetraethoxypropanes.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acetophenones / chemical synthesis*
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Acetophenones / chemistry
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Alcohols / chemistry
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Benzophenones / chemical synthesis*
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Benzophenones / chemistry
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Catalysis
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Chemistry, Organic / methods*
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Cyclization
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Ethers / chemistry
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Magnetic Resonance Spectroscopy
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Models, Chemical
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Models, Molecular
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Molecular Conformation
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Propane / chemistry*
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Salicylates / chemical synthesis*
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Salicylates / chemistry
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Stereoisomerism
Substances
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Acetophenones
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Alcohols
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Benzophenones
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Ethers
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Salicylates
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Propane