pi-electron ferromagnetism in metal-free carbon probed by soft x-ray dichroism

Phys Rev Lett. 2007 May 4;98(18):187204. doi: 10.1103/PhysRevLett.98.187204. Epub 2007 May 3.

Abstract

Elemental carbon represents a fundamental building block of matter and the possibility of ferromagnetic order in carbon has attracted widespread attention. However, the origin of magnetic order in such a light element is only poorly understood and has puzzled researchers. We present a spectromicroscopy study at room temperature of proton irradiated metal-free carbon using the elemental and chemical specificity of x-ray magnetic circular dichroism. We demonstrate that the magnetic order in the investigated system originates only from the carbon pi-electron system.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Carbon / chemistry*
  • Circular Dichroism
  • Electrons
  • Iron / chemistry*
  • Magnetics
  • Microscopy, Atomic Force
  • Spectrometry, X-Ray Emission

Substances

  • Carbon
  • Iron