(2S)-1-Carbamoylpyrrolidine-2-carboxylic acid

Acta Crystallogr C. 2007 May;63(Pt 5):o303-5. doi: 10.1107/S0108270107014102. Epub 2007 Apr 21.

Abstract

In the title compound, also known as N-carbamoyl-L-proline, C(6)H(10)N(2)O(3), the pyrrolidine ring adopts a half-chair conformation, whereas the carboxyl group and the mean plane of the ureide group form an angle of 80.1 (2) degrees. Molecules are joined by N-H...O and O-H...O hydrogen bonds into cyclic structures with graph-set R(2)(2)(8), forming chains in the b-axis direction that are further connected via N-H...O hydrogen bonds into a three-dimensional network.