Synthesis and luminescent properties of the lanthanide isothiocyanate complexes with an amide-type tripodal ligand

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jul;67(3-4):858-63. doi: 10.1016/j.saa.2006.08.044. Epub 2006 Sep 5.

Abstract

Solid complexes of lanthanide isothiocyanates with an amide-type tripodal ligand, 2,2',2''-nitrilotris-(N-phenylmethyl)-acetamide (L) have been synthesized and characterized by elemental analysis, infrared spectra and molar conductivity measurements. At the same time, the luminescent properties of the Sm(III), Eu(III), Tb(III), Dy(III) isothiocyanate complexes in solid state and the Tb(III) complex in solvents were also investigated.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetamides / chemistry*
  • Carbon / chemistry
  • Dysprosium / chemistry
  • Electric Conductivity
  • Electron Probe Microanalysis
  • Europium / chemistry
  • Hydrogen / chemistry
  • Isothiocyanates / chemical synthesis
  • Isothiocyanates / chemistry*
  • Lanthanoid Series Elements / chemistry*
  • Ligands
  • Luminescence*
  • Molecular Structure
  • Nitrogen / chemistry
  • Samarium / chemistry
  • Terbium / chemistry

Substances

  • Acetamides
  • Isothiocyanates
  • Lanthanoid Series Elements
  • Ligands
  • Terbium
  • Dysprosium
  • Samarium
  • Europium
  • Carbon
  • Hydrogen
  • Nitrogen