Much of the current uncertainty in the quantitative assessment of the climate and environment change is due to our lack of knowledge of the aerosol, for which the large-scale sun hazemeter ground-based network directly provides basic data. The data also can revise the results of the satellite remote sensing. Depending on the stations of CERN, the standard network was first built in China. The accurate and reliable hazemeter (LEDs) was uniformly used in the network. The hazemeters were calibrated by Langley plot method and transfer calibration and were uniformly checked. The AODs, which were synchronously retrieved from hazemeters (RSD < 3%) and CEMIL (RSD < 5%), were coherent and comparable. The stability and reliability of the hazemeters and the network was approved.