Abstract
The title compound, [Fe(C12H8N3O2)2]ClO4.2C2H3N, contains Fe(III) in a distorted octahedral coordination environment, with the Fe-N(pyridine) bonds significantly longer than the Fe-N(amine) bonds. The crystal packing involves a bifurcated C-H...(O,O) contact that is also found in all other [M(C12H8N3O2)2] complexes reported previously.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acetonitriles / chemistry*
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Crystallography, X-Ray
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Ferric Compounds / chemistry*
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Hydrogen Bonding
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Ions
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Iron / chemistry
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Ligands
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Molecular Conformation
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Perchlorates / chemistry
Substances
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Acetonitriles
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Ferric Compounds
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Ions
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Ligands
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Perchlorates
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bis(bis(2-pyridylcarbonyl)aminato)iron(III) perchlorate acetonitrile
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Iron
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perchlorate
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acetonitrile