Bis[bis(2-pyridylcarbonyl)aminato]iron(III) perchlorate acetonitrile disolvate

Acta Crystallogr C. 2006 Nov;62(Pt 11):m510-2. doi: 10.1107/S0108270106037310. Epub 2006 Oct 14.

Abstract

The title compound, [Fe(C12H8N3O2)2]ClO4.2C2H3N, contains Fe(III) in a distorted octahedral coordination environment, with the Fe-N(pyridine) bonds significantly longer than the Fe-N(amine) bonds. The crystal packing involves a bifurcated C-H...(O,O) contact that is also found in all other [M(C12H8N3O2)2] complexes reported previously.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetonitriles / chemistry*
  • Crystallography, X-Ray
  • Ferric Compounds / chemistry*
  • Hydrogen Bonding
  • Ions
  • Iron / chemistry
  • Ligands
  • Molecular Conformation
  • Perchlorates / chemistry

Substances

  • Acetonitriles
  • Ferric Compounds
  • Ions
  • Ligands
  • Perchlorates
  • bis(bis(2-pyridylcarbonyl)aminato)iron(III) perchlorate acetonitrile
  • Iron
  • perchlorate
  • acetonitrile