Attraction between like-charged walls: Short-ranged simulations using local molecular field theory

Phys Rev Lett. 2006 Sep 1;97(9):097801. doi: 10.1103/PhysRevLett.97.097801. Epub 2006 Aug 28.

Abstract

Effective attraction between like-charged walls mediated by counterions is studied using local molecular field (LMF) theory. Monte Carlo simulations of the "mimic system" given by LMF theory, with short-ranged "Coulomb core" interactions in an effective single particle potential incorporating a mean-field average of the long-ranged Coulomb interactions, provide a direct test of the theory, and are in excellent agreement with more complex simulations of the full Coulomb system by Moreira and Netz [Eur. Phys. J. E 8, 33 (2002)]. A simple, generally applicable criterion to determine the consistency parameter sigma(min) needed for accurate use of the LMF theory is presented.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemical Phenomena
  • Chemistry, Physical
  • Computer Simulation
  • DNA / chemistry
  • Electrochemistry*
  • Monte Carlo Method

Substances

  • DNA