[Water purification from ethylene glycol by catalytic oxidation using hydrogen peroxide]

Kosm Biol Aviakosm Med. 1991 May-Jun;25(3):52-5.
[Article in Russian]

Abstract

In order to select the method of water regeneration from air moisture condensate in a manned enclosed environment, the procedure of water decontamination from ethylene glycol was investigated. The process developed at t 20-22 degrees C and the following concentrations of C2H6O2 = 0.0125-0.5 mole/l, H2O2 = 1-5 mole/l, and catalyst = 1.7-50% wt. In the presence of 6.67 g/l of homogeneous catalyst FeSO4.7H2O, destructive oxidation of ethylene glycol to yield CO2 in the system 0.1 M C2H6O2 + 1M H2O2 proceeded effectively. However, the iron concentration in the decontaminated water exceeded significantly the maximally allowable concentration of iron in potable water as well as in industrial and non-industrial sewage. Heterogeneous MnO- and PbO-based catalysts provided no more than 20% ethylene glycol oxidation. Siderite, a natural mineral containing 33% wt. Fe2+, proved a more effective catalyst of ethylene glycol oxidation. When ethylene glycol and hydrogen peroxide were used at ratios of 1:30 and 1:80 with 5% wt. siderite, the degree of C2H6O2 to CO2 conversion was 99.2% and 99.8, respectively.

Publication types

  • Comparative Study

MeSH terms

  • Aerospace Medicine / methods
  • Aerospace Medicine / standards*
  • Catalysis / drug effects
  • Decontamination / methods
  • Ecological Systems, Closed*
  • Ethylene Glycol
  • Ethylene Glycols / isolation & purification*
  • Humans
  • Hydrogen Peroxide / pharmacology*
  • Iron / adverse effects
  • Iron / analysis
  • Lead / pharmacology
  • Manganese / pharmacology
  • Manganese Compounds*
  • Maximum Allowable Concentration
  • Oxides / pharmacology
  • Space Flight*
  • USSR
  • Water Pollutants, Chemical / isolation & purification*
  • Water Supply / analysis
  • Water Supply / standards*

Substances

  • Ethylene Glycols
  • Manganese Compounds
  • Oxides
  • Water Pollutants, Chemical
  • Lead
  • Manganese
  • lead oxide
  • manganese oxide
  • Hydrogen Peroxide
  • Iron
  • Ethylene Glycol