Abstract
The reaction of the Co(II) complex with the rigid bispidine ligand L1 with two tertiary amine and two pyridine donors, [Co(II)(L1)(OH2)2]2+, with H2O2 and O2 produces [Co(II)(L2)(OH2)2]3+, where L2 is demethylated at one of the amine donors, and CH2O.
MeSH terms
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Bridged Bicyclo Compounds, Heterocyclic / chemistry*
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Cobalt / chemistry*
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Dealkylation
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Hydrogen Peroxide / chemistry*
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Models, Chemical
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Oxidants / chemistry*
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Oxidation-Reduction
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Oxygen / chemistry*
Substances
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Bridged Bicyclo Compounds, Heterocyclic
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Oxidants
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bispidine
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Cobalt
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Hydrogen Peroxide
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Oxygen