Abstract
The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Alkanes / chemistry*
-
Alkenes / chemistry*
-
Carbon / chemistry
-
Catalysis
-
Models, Chemical
-
Nitro Compounds / chemistry*
-
Organometallic Compounds / chemistry*
-
Oxazoles / chemistry*
-
Thiazoles / chemistry*
-
Zinc / chemistry*
Substances
-
Alkanes
-
Alkenes
-
Nitro Compounds
-
Organometallic Compounds
-
Oxazoles
-
Thiazoles
-
Carbon
-
Zinc