Flavin-based [2]rotaxanes

Org Lett. 2006 May 25;8(11):2297-300. doi: 10.1021/ol060620q.

Abstract

[reaction: see text] We report the synthesis of flavin-stoppered hydrogen bonded [2]rotaxanes 1 and 2. We also report the electrochemically controllable properties of these systems in solution, and for derivative 2, as an electropolymerized thin film.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Crystallography, X-Ray
  • Electrochemistry / methods
  • Flavins / chemistry*
  • Hydrogen Bonding
  • Molecular Conformation
  • Molecular Structure
  • Rotaxanes / chemical synthesis*
  • Rotaxanes / chemistry*

Substances

  • Flavins
  • Rotaxanes