Hofmeister effects in supramolecular and biological systems

Biophys Chem. 2006 Dec 1;124(3):208-13. doi: 10.1016/j.bpc.2006.04.004. Epub 2006 Apr 26.

Abstract

Specific ion effects, representative of near-universal Hofmeister phenomena, are illustrated in three different systems. These are the formation of supramolecular assemblies from cyclodextrins, the optical rotation of L-serine, and the growth rate of two kinds of microorganisms (Staphylococcus aureus and Pseudomonas aeruginosa). The strong specific ion effects can be correlated with the anion polarizabilities and related physico-chemical parameters. The results show the relevance of dispersion (non-electrostatic) forces in these phenomena.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anions / pharmacology*
  • Cyclodextrins / chemistry*
  • Optical Rotation
  • Pseudomonas aeruginosa / drug effects*
  • Pseudomonas aeruginosa / growth & development
  • Serine / chemistry*
  • Serine / drug effects
  • Staphylococcus aureus / drug effects*
  • Staphylococcus aureus / growth & development

Substances

  • Anions
  • Cyclodextrins
  • Serine