The similarity of electric double-layer interaction from the general Poisson-Boltzmann theory

J Colloid Interface Sci. 2006 Aug 1;300(1):391-5. doi: 10.1016/j.jcis.2006.03.019. Epub 2006 Apr 24.

Abstract

We studied electric double-layer (EDL) interactions in electrolytes with different valence combinations. Our results show that the interactions are similar for electrolytes with the same co-ion valences and concentrations and such similarity increases with the co-ion valence and surface potential. A scaled surface potential was defined and found to be useful in characterizing the difference in EDL interaction. These results show that co-ions play a more important role than counterions in determining EDL potential and interaction in an electrolyte solution, especially for systems with high co-ion valence and/or high surface potentials.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Colloids / chemistry*
  • Models, Theoretical*
  • Solutions / chemistry
  • Static Electricity

Substances

  • Colloids
  • Solutions