Systematizing structural motifs and nomenclature in 1,n'-disubstituted ferrocene peptides

Chem Soc Rev. 2006 Apr;35(4):348-54. doi: 10.1039/b511332f. Epub 2006 Jan 23.

Abstract

Ferrocene peptide conjugates display an array of structural features including helical ferrocene based chirality and a number of different intramolecular hydrogen bonding patterns. In this tutorial review we present a rigorous nomenclature for these systems, followed by a section that summarises and categorises the structures known to date. The issues discussed herein are of general relevance for all metallocene-based chiral transition metal catalysts and peptide turn mimetics.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Ferrous Compounds / chemistry*
  • Hydrogen Bonding
  • Metallocenes
  • Models, Molecular
  • Molecular Structure
  • Peptides / chemistry*
  • Terminology as Topic*

Substances

  • Ferrous Compounds
  • Metallocenes
  • Peptides
  • ferrocene