Confinement effects on optical phonons in polar tetrapod nanocrystals detected by resonant inelastic light scattering

Nano Lett. 2006 Mar;6(3):478-82. doi: 10.1021/nl0524492.

Abstract

We investigated CdTe nanocrystal tetrapods of different sizes by resonant inelastic light scattering at room temperature and under cryogenic conditions. We observe a strongly resonant behavior of the phonon scattering with the excitonic structure of the tetrapods. Under resonant conditions we detect a set of phonon modes that can be understood as confined longitudinal-optical phonons, surface-optical phonons, and transverse-optical phonons in a nanowire picture.