Porphyrin dimers bridged by a platinum-diacetylide unit

Chem Commun (Camb). 2006 Mar 7:(9):1015-7. doi: 10.1039/b513921j. Epub 2006 Jan 23.

Abstract

A series of butadiyne- and platinum diacetylide-bridged conjugated porphyrin dimers have been prepared; electrochemical and UV-vis absorption measurements on these compounds show that the butadiyne-bridge confers stronger porphyrin-porphyrin conjugation than the platinum diacetylide-bridge.