"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes

Tomohiro Kato; Hitoshi Kuniyasu; Takamichi Kajiura; Yasunori Minami; Atsushi Ohtaka; Masanori Kinomoto; Jun Terao; Hideo Kurosawa; Nobuaki Kambe

doi:10.1039/b515616e

"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes

Chem Commun (Camb). 2006 Feb 28:(8):868-70. doi: 10.1039/b515616e. Epub 2006 Jan 18.

Authors

Tomohiro Kato¹, Hitoshi Kuniyasu, Takamichi Kajiura, Yasunori Minami, Atsushi Ohtaka, Masanori Kinomoto, Jun Terao, Hideo Kurosawa, Nobuaki Kambe

Affiliation

¹ Department of Applied Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka Suita, Osaka, 565-0871, Japan.

PMID: 16479294
DOI: 10.1039/b515616e

Abstract

Lone pair of heteroatom located at the beta-cis position in alpha,beta-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions.