Abstract
The binuclear [Ni(L)Fe(CO)3], , and trinuclear [Ni(L){Fe(CO)3}2], , complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via mu2-S bridging modes, C=N imine pi-bonds and potential Ni-Fe bonding interactions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Binding Sites
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Carbon Monoxide / chemistry*
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Crystallography, X-Ray
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Hydrogenase / chemistry*
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Hydrogenase / metabolism
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Imines / chemistry
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Iron Compounds / chemistry*
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Models, Chemical
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Nickel / chemistry*
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Sulfur Compounds / chemistry*
Substances
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Imines
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Iron Compounds
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Sulfur Compounds
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Nickel
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Carbon Monoxide
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nickel-iron hydrogenase
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Hydrogenase