Kinetics of RDX degradation by zero-valent iron (ZVI)

J Hazard Mater. 2006 Aug 10;136(1):68-74. doi: 10.1016/j.jhazmat.2005.11.015. Epub 2005 Dec 28.

Abstract

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) is a common groundwater contaminant at military facilities. The current research has been conducted to evaluate the use of zero-valent iron (ZVI) for the remediation of water contaminated with RDX. RDX was found to degrade rapidly in the presence of ZVI. The observed first-order kinetic constant for RDX reduction follows an enzymatic-like kinetic model with respect to the ZVI concentration. At low ZVI concentrations, RDX reduction follows pseudo first order kinetics with respect to ZVI concentration; while at high ZVI concentrations the RDX reduction is zero-order. Nitroso compounds (MNX, DNX, and TNX), nitrate, nitrite and nitrous oxide were identified as the main by-products for the RDX reduction by ZVI. The nitroso compounds were found to undergo reduction by ZVI.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Iron / chemistry*
  • Kinetics
  • Nitrates / chemistry
  • Nitrites / chemistry
  • Oxidation-Reduction
  • Triazines / chemistry*

Substances

  • Nitrates
  • Nitrites
  • Triazines
  • Iron
  • cyclonite