Effect of surface acoustic waves on the catalytic decomposition of ethanol employing a comb transducer for ultrasonic generation

Ultrason Sonochem. 2006 Apr;13(3):283-6. doi: 10.1016/j.ultsonch.2005.09.011. Epub 2005 Dec 15.

Abstract

The effect of surface acoustic waves, generated on a silver catalyst using a comb transducer, on the catalytic decomposition of ethanol is examined. The comb transducer employs purely mechanical means for surface acoustic wave (SAW) transduction. Unlike interdigital SAW transducers on piezoelectric substrates, the complicating effects of heat generation due to electromechanical coupling, high electric fields between adjacent electrodes, and acoustoelectric currents are avoided. The ethanol decomposition reactions are carried out at 473 K. The rates of acetaldehyde and ethylene production are retarded when acoustic waves are applied. The rates recover to varying degrees when acoustic excitation ceases.