17O NMR spectra of some organotin(IV) compounds containing O,C,O-chelating ligands

Libor Dostál; Roman Jambor; Ales Růzicka; Antonín Lycka; Jaroslav Holecek

doi:10.1002/mrc.1743

17O NMR spectra of some organotin(IV) compounds containing O,C,O-chelating ligands

Magn Reson Chem. 2006 Feb;44(2):171-3. doi: 10.1002/mrc.1743.

Authors

Libor Dostál¹, Roman Jambor, Ales Růzicka, Antonín Lycka, Jaroslav Holecek

Affiliation

¹ Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, nám. Cs. legií 565, CZ-532 10, Pardubice, Czech Republic.

PMID: 16358304
DOI: 10.1002/mrc.1743

Abstract

The 17O chemical shifts of substituted benzyl ethers and a set of organotin(IV) derivatives containing O,C,O-chelating ligands were studied. Measured 17O chemical shifts were correlated with the additivity substituent increments for carbon atoms in the alkyl groups, and intramolecular Sn-O distance was obtained by X-ray diffraction techniques in the solid state.