The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4

Chem Commun (Camb). 2005 Oct 28:(40):5041-3. doi: 10.1039/b510636b. Epub 2005 Sep 15.

Abstract

The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aziridines / chemistry*
  • Cross-Linking Reagents / chemistry
  • Hydrogen / chemistry
  • Macrocyclic Compounds / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Nitrogen / chemistry

Substances

  • Aziridines
  • Cross-Linking Reagents
  • Macrocyclic Compounds
  • Hydrogen
  • Nitrogen