Groundwater contamination by chlorinated naphthalenes and related substances caused by activities of a former military base

Chemosphere. 2005 Nov;61(6):770-82. doi: 10.1016/j.chemosphere.2005.04.010. Epub 2005 Jun 6.

Abstract

Water samples derived from two different aquifer layers of six sampling sites were analysed by GC/MS in order to characterize a groundwater contamination caused by chemicals used for wood impregnation. Mono- and dichlorinated naphthalenes, chlorobenzo(b)thiophene, 1-chloro-4-naphthol, 1-chloronaphthoic acid, acenaphthene and methyled naphthalenes were identified as the main pollutants and quantified. 1-Chloro-4-naphthol and 1-chloronaphthoic acid are discussed as possible indicators for anaerobic degradation processes. Results of inorganic and compound specific stable carbon isotope analyses revealed only a minor degree of microbiological transformation. Thus, sorption was characterized as the main attenuation process within the aquifer affecting the contamination described.

MeSH terms

  • Acenaphthenes / analysis
  • Adsorption
  • Atrazine / analysis
  • Bacteria, Anaerobic / metabolism
  • Biodegradation, Environmental
  • Bromouracil / analogs & derivatives
  • Bromouracil / analysis
  • Carbon Isotopes
  • Fresh Water / analysis
  • Gas Chromatography-Mass Spectrometry
  • Herbicides / analysis
  • Naphthalenes / analysis*
  • Naphthalenes / chemistry
  • Naphthalenes / metabolism
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / metabolism

Substances

  • Acenaphthenes
  • Carbon Isotopes
  • Herbicides
  • Naphthalenes
  • Water Pollutants, Chemical
  • Bromouracil
  • bromacil
  • Atrazine