Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride

Org Lett. 2005 Jun 9;7(12):2405-8. doi: 10.1021/ol0506821.

Abstract

[reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Furans / chemistry*
  • Molecular Structure
  • Quaternary Ammonium Compounds / chemistry*
  • Silanes / chemistry*
  • Structure-Activity Relationship

Substances

  • Furans
  • Quaternary Ammonium Compounds
  • Silanes
  • silanol
  • tetrabutylammonium