Gold nanoparticles quench fluorescence by phase induced radiative rate suppression

Nano Lett. 2005 Apr;5(4):585-9. doi: 10.1021/nl0480969.

Abstract

The fluorescence quantum yield of Cy5 molecules attached to gold nanoparticles via ssDNA spacers is measured for Cy5-nanoparticle distances between 2 and 16 nm. Different numbers of ssDNA per nanoparticle allow to fine-tune the distance. The change of the radiative and nonradiative molecular decay rates with distance is determined using time-resolved photoluminescence spectroscopy. Remarkably, the distance dependent quantum efficiency is almost exclusively governed by the radiative rate.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbocyanines / chemistry*
  • DNA, Single-Stranded / chemistry*
  • Fluorescence
  • Fluorescent Dyes / chemistry*
  • Gold / chemistry*
  • Nanostructures / chemistry*

Substances

  • Carbocyanines
  • DNA, Single-Stranded
  • Fluorescent Dyes
  • cyanine dye 5
  • Gold