Thioureas as ligands in the pd-catalyzed intramolecular Pauson-Khand reaction

Yefeng Tang; Lujiang Deng; Yangdong Zhang; Guangbin Dong; Jiahua Chen; Zhen Yang

doi:10.1021/ol050410y

Thioureas as ligands in the pd-catalyzed intramolecular Pauson-Khand reaction

Org Lett. 2005 Apr 14;7(8):1657-9. doi: 10.1021/ol050410y.

Authors

Yefeng Tang¹, Lujiang Deng, Yangdong Zhang, Guangbin Dong, Jiahua Chen, Zhen Yang

Affiliation

¹ Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Beijing 100871, China.

PMID: 15816776
DOI: 10.1021/ol050410y

Abstract

[reaction: see text] The thiourea-Pd complex was established as a novel type of catalyst in the PKR of allylpropargylamine, and the demonstrated chemistry may prove to be valuable for developing thiuorea as a ligand for the Pd-catalyzed Pauson-Khand reaction.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Heterocyclic Compounds, 2-Ring / chemical synthesis*
Ligands
Molecular Structure
Palladium / chemistry*
Propylamines / chemistry
Thiourea / chemistry*

Substances

Heterocyclic Compounds, 2-Ring
Ligands
Propylamines
Palladium
Thiourea