NaI-catalyzed highly regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines: highly stereoselective synthesis of cis-vinylic aziridines

Chem Commun (Camb). 2005 Feb 21:(7):909-11. doi: 10.1039/b413807d. Epub 2005 Jan 5.

Abstract

cis-Vinylic aziridines were prepared highly stereoselectively via a NaI-catalyzed regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aziridines / chemical synthesis*
  • Aziridines / chemistry
  • Catalysis
  • Crystallography, X-Ray
  • Cyclization
  • Cyclopropanes / chemistry*
  • Imines / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Sodium Iodide / chemistry*
  • Stereoisomerism

Substances

  • Aziridines
  • Cyclopropanes
  • Imines
  • cyclopropene
  • Sodium Iodide