Double-quantum filtered 1H MAS NMR spectra

Solid State Nucl Magn Reson. 2005 May;27(3):174-9. doi: 10.1016/j.ssnmr.2004.11.001.

Abstract

It is shown that straightforward double-quantum filtered (1)H MAS NMR experiments yield spectral lineshapes that permit to estimate the minimum number of (1)H spins in a cluster. The approach may offer an alternative to multiple-quantum experiments for the characterisation of (1)H spin clusters of moderate size. The duration of the double-quantum excitation period has to be chosen suitably, it is necessary to find a practical compromise between optimum double-quantum filtration efficiency and optimum information content of the spectral lineshapes. Some (1)H MAS NMR experiments on partially deuterated maleic acid are reported as well as numerical simulations.

Publication types

  • Comparative Study
  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Algorithms*
  • Computer Simulation
  • Deuterium / analysis
  • Deuterium / chemistry
  • Magnetic Resonance Spectroscopy / methods*
  • Maleates / analysis*
  • Maleates / chemistry*
  • Models, Chemical*
  • Models, Molecular*
  • Protons*

Substances

  • Maleates
  • Protons
  • maleic acid
  • Deuterium