Bis(2-amino-6-methylpyridinium) tetrachlorozincate(II)

Acta Crystallogr C. 2005 Jan;61(Pt 1):m43-5. doi: 10.1107/S0108270104030458. Epub 2004 Dec 18.

Abstract

The title compound, (C6H9N2)2[Zn(II)Cl4], consists of two 2-amino-6-methylpyridinium (AMP) cations and one [ZnCl4]2- anion, which are held together by N-H...Cl hydrogen bonds. Bond lengths within the AMP cation indicate that the imine tautomer makes a significant contribution to the structure. The molecules are associated by two different pi-pi interactions between identical antiparallel AMP cations, with face-to-face distances of 3.627 (4) and 3.342 (3) A, to form a one-dimensional chain.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aminopyridines / chemistry*
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Pyridinium Compounds / chemistry*
  • Zinc / chemistry*

Substances

  • Aminopyridines
  • Organometallic Compounds
  • Pyridinium Compounds
  • Zinc