Synthesis of a hafnocene disilene complex

Roland Fischer; Michaela Zirngast; Michaela Flock; Judith Baumgartner; Christoph Marschner

doi:10.1021/ja0464387

Synthesis of a hafnocene disilene complex

J Am Chem Soc. 2005 Jan 12;127(1):70-1. doi: 10.1021/ja0464387.

Authors

Roland Fischer¹, Michaela Zirngast, Michaela Flock, Judith Baumgartner, Christoph Marschner

Affiliation

¹ Institut für Anorganische Chemie, Technische Universität Graz, A-8010 Graz, Stremayrgasse 16/IV, Austria.

PMID: 15631453
DOI: 10.1021/ja0464387

Abstract

Reaction of the magnesium transmetalation product of a 1,2-dipotassiodisilane with hafnocene dichloride gives a disilene hafnocene complex. X-ray crystallography of the respective trimethylphosphane adduct provides structural proof for this assignment.