Role of the orbitally degenerate Mn(III) ions in the single-molecule magnet behavior of the cyanide cluster ([MnII(tmphen)2]3[Mn(III)(CN)6]2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)

Andrei V Palii; Sergei M Ostrovsky; Sophia I Klokishner; Boris S Tsukerblat; Curtis P Berlinguette; Kim R Dunbar; José Ramón Galán-Mascarós

doi:10.1021/ja046771a

Role of the orbitally degenerate Mn(III) ions in the single-molecule magnet behavior of the cyanide cluster ([MnII(tmphen)2]3[Mn(III)(CN)6]2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)

J Am Chem Soc. 2004 Dec 29;126(51):16860-7. doi: 10.1021/ja046771a.

Authors

Andrei V Palii¹, Sergei M Ostrovsky, Sophia I Klokishner, Boris S Tsukerblat, Curtis P Berlinguette, Kim R Dunbar, José Ramón Galán-Mascarós

Affiliation

¹ Institute of Applied Physics, Academy of Sciences of Moldova, Academy Str. 5, MD 2028 Kishinev, Moldova. Andrew.Palli@uv.es

PMID: 15612725
DOI: 10.1021/ja046771a

Abstract

We report a new theoretical model that accounts for the unusual magnetic properties of the cyanide cluster ([MnII(tmphen)2]3[MnIII(CN)6]2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). The model takes into account (1) the spin-orbit interaction, (2) the trigonal component of the crystal field acting on the ground-state cubic (3)T(1) terms of the apical Mn(III) ions, and (3) the isotropic contribution to the exchange interaction between Mn(III) and Mn(II) ions. The ground state of the cluster was shown to be the state with the total angular momentum projection |M(J)| = 15/2; the energies of the low-lying levels obtained from this treatment increase with decreasing |M(J)| values, a situation that leads to a barrier for the reversal of magnetization (U(eff) approximately 30 cm(-1)). The new model explains the recently discovered single-molecule magnet behavior of the ([MnII(tmphen)2]3[MnIII(CN)6]2)in contrast to the traditional approach that takes into account only the ground-state spin (S) and a negative zero-field splitting parameter (D(S) < 0).