Removal of industrial cutting oil from oil emulsions by polymeric ultra- and microfiltration membranes

Environ Sci Technol. 2004 Sep 15;38(18):4878-83. doi: 10.1021/es0348243.

Abstract

The utilization of micro- and ultrafiltration with polymeric membranes for treatment of industrial cutting oil emulsion was investigated. The performance of 14 different membranes with pore sizes in the range of 1-800 nm, representing 8 different materials and varying hydrophobicity, was determined experimentally. Membrane permeances between 1.6 and 939 L m 2 h(-1) bar(-1) have been observed for the different samples as well as oil rejections between 3.42% and 99.99%. Membrane pore size and contact angle showed little influence on both values, while an interesting correlation is displayed to the individual membranes' capillary pressures. A possible explanation for this phenomenon is suggested based on the formation of oil films on the membrane surface. From the investigated membranes, the best-suited one for cutting oil treatment was selected and subjected to further experiments. The effect of process temperatures between 22 and 43 degrees C and of feed oil concentrations between 0 and 20 vol % on the removal performance was determined. The results correspond to the explanation suggested previously.

Publication types

  • Comparative Study

MeSH terms

  • Emulsions / analysis*
  • Emulsions / chemistry
  • Hot Temperature
  • Hydrophobic and Hydrophilic Interactions
  • Industrial Oils / analysis*
  • Membranes, Artificial*
  • Permeability
  • Polymers / chemistry*
  • Porosity
  • Ultrafiltration / instrumentation
  • Ultrafiltration / methods*

Substances

  • Emulsions
  • Membranes, Artificial
  • Polymers