Structures of new secofriedelane and friedelane acids from Calophyllum inophyllum of French Polynesia

F Laure; G Herbette; R Faure; J P Bianchini; P Raharivelomanana; B Fogliani

doi:10.1002/mrc.1476

Structures of new secofriedelane and friedelane acids from Calophyllum inophyllum of French Polynesia

Magn Reson Chem. 2005 Jan;43(1):65-8. doi: 10.1002/mrc.1476.

Authors

F Laure¹, G Herbette, R Faure, J P Bianchini, P Raharivelomanana, B Fogliani

Affiliation

¹ Laboratoire de Chimie Analytique Appliquée, Université de la Polynésie Française, BP 6570, 98702 Faaa, Tahiti, French Polynesia.

PMID: 15468303
DOI: 10.1002/mrc.1476

Abstract

Three new friedelane-type triterpenoids, 3,4-secofriedelan-3,28-dioic acid (1), 27-hydroxyacetate canophyllic acid (2) and 3-oxo-27-hydroxyacetate friedelan-28-oic acid (3), were isolated from the leaves of Calophyllum inophyllum (Clusiaceae) grown in French Polynesia. Their structures were established by the concerted application of 2D NMR techniques including gs-COSY, gs-HMQC and gs-HMBC.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Calophyllum / chemistry*
Magnetic Resonance Spectroscopy / methods
Models, Molecular
Molecular Conformation
Polynesia
Terpenes / chemistry*
Triterpenes / chemistry

Substances

Terpenes
Triterpenes
friedelane