Advanced phosphorus removal from membrane filtrates by adsorption on activated aluminium oxide and granulated ferric hydroxide

Water Res. 2004 Sep;38(16):3523-30. doi: 10.1016/j.watres.2004.06.006.

Abstract

The advanced phosphorus (P) removal by adsorption was studied for its suitability as a post-treatment step for membrane bioreactor (MBR) effluents low in P concentration and particle content. Two commercial adsorbents, granulated ferric hydroxide (GFH) and activated aluminium oxide (AA), were studied in batch tests and lab-scale filter tests for P adsorption in MBR filtrates. GFH showed a higher maximum capacity for phosphate and a higher affinity at low P concentrations compared to AA. Competition by inorganic ions was negligible for both adsorbents at the original pH (8.2). When equilibrium P concentrations exceeded 2 mg L(-1) in the spiked MBR filtrates, a precipitation of calcium phosphates occurred additionally to adsorption. During column studies the effluent criteria of 50 microgL(-1) P was reached after a throughput of 8000 bed volumes for GFH and 4000 for AA. Dissolved organic carbon appears to be the strongest competitor for adsorption sites. A partial regeneration and reloading of both adsorbents could be achieved by the use of sodium hydroxide.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Aluminum Oxide / chemistry
  • Ferric Compounds / chemistry
  • Filtration
  • Membranes, Artificial
  • Phosphorus / isolation & purification*
  • Temperature
  • Waste Disposal, Fluid
  • Water Purification / methods*

Substances

  • Ferric Compounds
  • Membranes, Artificial
  • Phosphorus
  • ferric hydroxide
  • Aluminum Oxide