Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

Chem Commun (Camb). 2004 Aug 21:(16):1880-1. doi: 10.1039/b405358c. Epub 2004 Jul 7.

Abstract

An unusual copper(ii) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.