Abstract
A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of Lambda-[FeL(3)](2+) complexes; interconversion of Delta and Lambda cations is relatively fast, and in CHCl(3), the favored complexes with Delta- or Lambda-TRISPHAT counterions are homochiral, (Delta(+)Delta(-)) or (Lambda(+)Lambda(-)). In the case of the Delta-TRISPHAT salt, a single diastereomer is observed (de > or = 96%).
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Circular Dichroism
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Ferrous Compounds / chemical synthesis*
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Ferrous Compounds / chemistry*
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Ligands
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Organophosphorus Compounds / chemistry*
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Ribose* / analogs & derivatives
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Ribose* / analysis
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Ribose* / chemical synthesis
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Ribose* / chemistry
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Stereoisomerism
Substances
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Ferrous Compounds
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Ligands
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Organophosphorus Compounds
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tris(tetrachlorobenzenediolato)phosphate(V)
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Ribose