Direct syntheses of S-alkylthio-D-galactono-, D-mannono-1,4-lactones, S-alkylthio-L-galactitols and D-mannitols displaying amphiphilic and mesophasic properties

Ludovic Chaveriat; Imane Stasik; Gilles Demailly; Daniel Beaupère

doi:10.1016/j.carres.2004.05.004

Direct syntheses of S-alkylthio-D-galactono-, D-mannono-1,4-lactones, S-alkylthio-L-galactitols and D-mannitols displaying amphiphilic and mesophasic properties

Carbohydr Res. 2004 Jul 12;339(10):1817-21. doi: 10.1016/j.carres.2004.05.004.

Authors

Ludovic Chaveriat¹, Imane Stasik, Gilles Demailly, Daniel Beaupère

Affiliation

¹ Laboratoire des Glucides (FRE 2779), Université de Picardie Jules Verne, 33 Rue Saint-Leu, F-80039 Amiens, France.

PMID: 15220093
DOI: 10.1016/j.carres.2004.05.004

Abstract

Alkylthio-L-galactitols and D-mannitols were obtained in good yields (70-81%) by reduction, with NaBH4, of the corresponding 6-S-alkyl-6-thio-D-hexono-1,4-lactones.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbohydrate Conformation
Carbohydrates / chemistry
Galactose / chemistry*
Lactones / chemistry*
Magnetic Resonance Spectroscopy
Mannitol / chemistry*
Models, Chemical
Spectrophotometry
Sulfhydryl Compounds / chemistry
Temperature
Ultraviolet Rays

Substances

Carbohydrates
Lactones
Sulfhydryl Compounds
Mannitol
Galactose