Cylindrical molecular brushes under poor solvent conditions: microscopic observation and scaling analysis

Eur Phys J E Soft Matter. 2004 Feb;13(2):125-31. doi: 10.1140/epje/e2004-00049-8.

Abstract

Axial contraction of cylindrical molecular brushes of polymethylmethacrylate was observed by static light scattering and scanning force microscopy. Single brush molecules were visualized as worm-like particles whose length was almost three times shorter than the contour length of the backbone. A somewhat larger length was measured by light scattering in a good solvent. A scaling approach has been used to analyze the driving forces for the axial contraction and the conformation of the molecular brushes.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Aluminum Silicates / chemistry
  • Chloroform / chemistry
  • Light
  • Macromolecular Substances
  • Magnetics
  • Microscopy, Atomic Force / methods*
  • Models, Statistical
  • Polymers / chemistry
  • Polymethyl Methacrylate / chemistry
  • Scattering, Radiation
  • Solvents*
  • Thermodynamics

Substances

  • Aluminum Silicates
  • Macromolecular Substances
  • Polymers
  • Solvents
  • Chloroform
  • Polymethyl Methacrylate
  • mica