[Ag6(PMo10V2O40](CH3COO).8H2O: A 3D macrocationic polyoxometallic Keggin complex

Feng-Xian Liu; Catherine Marchal-Roch; Philippe Bouchard; Jérôme Marrot; Jean-Pierre Simonato; Gilbert Hervé; Francis Sécheresse

doi:10.1021/ic035313k

[Ag6(PMo10V2O40](CH3COO).8H2O: A 3D macrocationic polyoxometallic Keggin complex

Inorg Chem. 2004 Apr 5;43(7):2240-2. doi: 10.1021/ic035313k.

Authors

Feng-Xian Liu¹, Catherine Marchal-Roch, Philippe Bouchard, Jérôme Marrot, Jean-Pierre Simonato, Gilbert Hervé, Francis Sécheresse

Affiliation

¹ Institut de Réactivité, Electrochimie et Microporosités, UMR CNRS 8637, Université de Versailles-St Quentin-en-Yvelines, Bâtiment Lavoisier, 45, Avenue des Etats-Unis, 78035 Versailles Cedex, France.

PMID: 15046496
DOI: 10.1021/ic035313k

Abstract

Silver atoms and strongly interlinking Keggin units ensure the tridimensionnal macrocationic structure of [Ag(6)(PMo(10)V(2)O(40))](CH(3)COO).8H(2)O, which catalyzes O(2)-based oxidation of p-methoxytoluene in acetic acid by air.