Unprecedented photochemical induced cascading rearrangement of the 3-azabicyclo[3.3.1]nonane skeleton

Craig M Williams; Ralf Heim; Douglas J Brecknell; Paul V Bernhardt

doi:10.1039/b402200a

Unprecedented photochemical induced cascading rearrangement of the 3-azabicyclo[3.3.1]nonane skeleton

Org Biomol Chem. 2004 Mar 21;2(6):806-7. doi: 10.1039/b402200a. Epub 2004 Feb 19.

Authors

Craig M Williams¹, Ralf Heim, Douglas J Brecknell, Paul V Bernhardt

Affiliation

¹ Chemistry Department, School of Molecular and Microbial Sciences, University of Queensland, St. Lucia, 4072, Queensland, Australia. c.williams3@mailbox.uq.edu.au

PMID: 15007404
DOI: 10.1039/b402200a

Abstract

Certain 3-azabicyclo[3.3.1]nonane derivatives undergo unprecedented stereospecific skeletal cleavage when subjected to light affording a novel heterotricyclic skeleton.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkanes / chemistry*
Aza Compounds / chemistry*
Bridged Bicyclo Compounds, Heterocyclic / chemistry*
Bridged-Ring Compounds / chemistry*
Molecular Structure
Photochemistry
Stereoisomerism

Substances

Alkanes
Aza Compounds
Bridged Bicyclo Compounds, Heterocyclic
Bridged-Ring Compounds
nonane