Domino 'Staudinger-aza-Wittig-1,5-phosphonium-rearrangement-fragmentation' reactions of 1-azido-2-hydroxy-4,6-dioxohexanes

Peter Langer; Ilia Freifeld; Heydar Shojaei

doi:10.1039/b310701a

Domino 'Staudinger-aza-Wittig-1,5-phosphonium-rearrangement-fragmentation' reactions of 1-azido-2-hydroxy-4,6-dioxohexanes

Chem Commun (Camb). 2003 Dec 21:(24):3044-5. doi: 10.1039/b310701a.

Authors

Peter Langer¹, Ilia Freifeld, Heydar Shojaei

Affiliation

¹ Institut für Chemie und Biochemie der Ernst-Moritz-Arndt Universität Greifswald, Soldmannstr. 16, D-17487 Greifswald, Germany. peter.langer@uni-greifswald.de

PMID: 14703849
DOI: 10.1039/b310701a

Abstract

The domino 'Staudinger-aza-Wittig-1,5-phosphonium-rearrangement-fragmentation' reaction of 1-azido-2-hydroxy-4,6-dioxohexanes allows a convenient synthesis of functionalized 1-acetamido-2-alkylidenecyclopentanes.