A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes

Antonio Alberola; Eugenio Coronado; José R Galán-Mascarós; Carlos Giménez-Saiz; Carlos J Gómez-García

doi:10.1021/ja035772k

A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes

J Am Chem Soc. 2003 Sep 10;125(36):10774-5. doi: 10.1021/ja035772k.

Authors

Antonio Alberola¹, Eugenio Coronado, José R Galán-Mascarós, Carlos Giménez-Saiz, Carlos J Gómez-García

Affiliation

¹ Instituto de Ciencia Molecular, Universidad de Valencia, Dr Moliner, 50, Burjassot, E-46100 Spain.

PMID: 12952442
DOI: 10.1021/ja035772k

Abstract

A new dual-function hybrid molecular material has been obtained from the organic donor bis(ethylenedithio)tetraselenafulvalene and the honeycomb oxalate-based bimetallic network [MnCr(ox)3]-. This multilayer material consists of layers of the inorganic anionic 2D network, responsible for the appearance of ferromagnetic ordering below 5.3 K, alternating with segregated layers of the organic cation radical responsible for the transport properties: metal-like conductivity is observed from room temperature down to 150 K.