The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E(2)Cr(2)Fe(CO)(10)](2-) (E = Te, Se)

Minghuey Shieh; Ren-Ling Chung; Chun-Hsien Yu; Miao-Hsing Hsu; Chia-Hua Ho; Shie-Ming Peng; Yi-Hung Liu

doi:10.1021/ic034081m

The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E(2)Cr(2)Fe(CO)(10)](2-) (E = Te, Se)

Inorg Chem. 2003 Sep 8;42(18):5477-9. doi: 10.1021/ic034081m.

Authors

Minghuey Shieh¹, Ren-Ling Chung, Chun-Hsien Yu, Miao-Hsing Hsu, Chia-Hua Ho, Shie-Ming Peng, Yi-Hung Liu

Affiliation

¹ Departments of Chemistry, National Taiwan Normal University, Taipei, Taiwan, 116, Republic of China. mshieh@scc.ntnu.edu.tw

PMID: 12950191
DOI: 10.1021/ic034081m

Abstract

The rare examples of electron-rich mixed-metal carbonyl telluride and selenide clusters [E(2)Cr(2)Fe(CO)(10)](2-) (E = Te, Se) have been demonstrated. These two novel carbonyl complexes exhibit the unusual paramagnetic behavior.