Possible existence of a higher coverage quasi-one-dimensional phase of argon adsorbed on bundles of single-walled carbon nanotubes

J Nanosci Nanotechnol. 2002 Oct;2(5):467-70. doi: 10.1166/153348802760394007.

Abstract

We present results of Ar adsorption isotherms at very low coverages in the first layer and, beyond monolayer completion, on bundles of close-ended single-walled carbon nanotubes. The low coverage results were used to determine the isosteric heat of adsorption and the binding energy of Ar in the groove sites in the first layer. The higher coverage results show evidence of the possible formation of a second-layer groove phase, beyond monolayer completion. Our results for higher coverages are compared with recent computer simulations for this system.

Publication types

  • Comparative Study
  • Evaluation Study
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Validation Study

MeSH terms

  • Adsorption
  • Argon / chemistry*
  • Computer Simulation
  • Membranes, Artificial
  • Models, Molecular*
  • Nanotechnology / methods*
  • Nanotubes, Carbon / chemistry*
  • Pressure
  • Temperature

Substances

  • Membranes, Artificial
  • Nanotubes, Carbon
  • Argon