A novel open framework uranyl molybdate: synthesis and structure of (NH4)4[(UO2)5(MoO4)7](H2O)5

S V Krivovichev; C L Cahill; P C Burns

doi:10.1021/ic020516e

A novel open framework uranyl molybdate: synthesis and structure of (NH4)4[(UO2)5(MoO4)7](H2O)5

Inorg Chem. 2003 Apr 7;42(7):2459-64. doi: 10.1021/ic020516e.

Authors

S V Krivovichev¹, C L Cahill, P C Burns

Affiliation

¹ Department of Civil Engineering and Geological Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, Indiana 46556, USA.

PMID: 12665384
DOI: 10.1021/ic020516e

Abstract

Single crystals of (NH(4))(4)[(UO(2))(5)(MoO(4))(7)](H(2)O)(5) have been synthesized hydrothermally using (NH(4))(6)Mo(7)O(24), (UO(2))(CH(3)COO)(2).2H(2)O, and H(2)O at 180 degrees C. The phase has been characterized by single-crystal X-ray diffraction using a merohedrally twinned single crystal: it is hexagonal, P6(1), a = 11.4067(5) A, c = 70.659(5) A, V = 7961.9(7) A(3), and Z = 6. The structure is based upon an open framework with composition [(UO(2))(5)(MoO(4))(7)](4-) that is composed of UO(7) pentagonal bipyramids that share vertexes with MoO(4) tetrahedra. The framework has large channels (effective pore size: 4.8 x 4.8 A(2)) parallel to the c axis and a system of smaller channels (effective pore size: 2.5 x 3.6 A(2)) parallel to [100], [110], [010], [110], [110], and [110]. The channels are occupied by NH(4)(+) cations and H(2)O molecules. The topological structure of the uranyl molybdate framework can be described either in terms of fundamental chains of UO(7) pentagonal bipyramids and MoO(4) tetrahedra or in terms of tubular building units parallel to the c axis.