Degradation of the adsorbent Tenax TA by nitrogen oxides, ozone, hydrogen peroxide, OH radical, and limonene oxidation products

Environ Sci Technol. 2002 Oct 1;36(19):4121-6. doi: 10.1021/es025680f.

Abstract

The degradation of the adsorbent Tenax TA was studied qualitatively by sampling oxidants common in indoor air followed by thermal desorption and gas chromatography. A total of 25 degradation products were identified. Several degradation products not reported previously were identified: 9 for nitrogen dioxide; 11 for ozone; 2 for hydrogen peroxide; 12 for hydroxyl radical; 1 for ozone-limonene mixtures, but none for nitrogen oxide. Whereas ozone shows a complex degradation of the adsorbent, hydrogen peroxide and limonene--ozone mixtures show few products. Nitrogen dioxide and the hydroxyl radical behave almost identically and produce 2,6-diphenyl-p-benzoquinone as the major degradation product. Reactant specific degradation products were identified for ozone (11) and nitrogen dioxide (1).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Air Pollutants
  • Carcinogens / chemistry*
  • Chromatography, Gas
  • Cyclohexenes
  • Hydrogen Peroxide / chemistry*
  • Hydroxyl Radical / chemistry*
  • Limonene
  • Nitrogen Oxides / chemistry*
  • Oxidants / chemistry*
  • Oxidants, Photochemical / chemistry*
  • Ozone / chemistry*
  • Polymers / chemistry*
  • Temperature
  • Terpenes / chemistry*

Substances

  • Air Pollutants
  • Carcinogens
  • Cyclohexenes
  • Nitrogen Oxides
  • Oxidants
  • Oxidants, Photochemical
  • Polymers
  • Terpenes
  • tenax
  • Hydroxyl Radical
  • Ozone
  • Limonene
  • Hydrogen Peroxide