Abstract
Serine-O-carbonate derivatives, including peptides having a serine-O-carbonate residue at the N-terminal position, are catalytically transformed into S-substituted cysteine derivatives employing the pyridoxal model having an ionophore function in the presence of Li+; this is the first artificial model mimicking cystathionine Beta-synthase.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carbonates / chemistry*
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Catalysis
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Cystathionine beta-Synthase / metabolism
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Cysteine / chemistry
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Ionophores / chemistry*
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Lithium
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Molecular Structure
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Peptides / chemistry
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Pyridoxal / chemistry*
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Serine / analogs & derivatives*
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Serine / chemistry*
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Sulfhydryl Compounds / chemistry*
Substances
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Carbonates
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Ionophores
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Peptides
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Sulfhydryl Compounds
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Pyridoxal
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Serine
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Lithium
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Cystathionine beta-Synthase
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Cysteine