Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterizations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

S Triki; F Thétiot; J S Pala; S Golhen; J M Clemente-Juan; C J Gómez-García; E Coronado

doi:10.1039/b105231b

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterizations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

Chem Commun (Camb). 2001 Nov 7:(21):2172-3. doi: 10.1039/b105231b.

Authors

S Triki¹, F Thétiot, J S Pala, S Golhen, J M Clemente-Juan, C J Gómez-García, E Coronado

Affiliation

¹ UMR CNRS 6521, Univ. de Bretagne Occidentale, BP 809, 29285 Brest, France. smail.triki@univ-brest.fr

PMID: 12240097
DOI: 10.1039/b105231b

Abstract

A new polynuclear copper(II) complex [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.