Abstract
[reaction: see text] A stereoselective synthesis of 6-8-6 fused carbocyclic systems based on enol alkylation, ketone allylation, RCM, and Heck cyclization was developed to obtain compounds with a carbon framework that mimics the putative transition structure of the isomerization of previtamin D3 to vitamin D3.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cholecalciferol / analogs & derivatives*
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Cholecalciferol / chemistry*
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Indicators and Reagents
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Isomerism
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Models, Molecular
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Oxidation-Reduction
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Polycyclic Aromatic Hydrocarbons / chemistry*
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Stereoisomerism
Substances
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Indicators and Reagents
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Polycyclic Aromatic Hydrocarbons
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Cholecalciferol
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previtamin D(3)